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HomeMIT 2.43 Advanced Thermodynamics, Spring 2024Lecture 16: Liquid-Vapor Equilibria in Mixtures; Ideal and Excess Chemical Potentials

Lecture 16: Liquid-Vapor Equilibria in Mixtures; Ideal and Excess Chemical Potentials

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Liquid-vapor equilibria in mixtures. Raoult’s law. Dew line and bubble line. Distillation. Freezing point depression. Boiling point elevation. Non-ideal mixtures. The Duhem-Margules relations. Ideal and excess Gibbs free energy and chemical potentials.